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Design d'un iprodione-MIP (molecularly imprinted polymer) : application à la pré-concentration des fongicides dans le vin

2014

The aim of this study was the synthesis of a MIP (molecularly imprinted polymer) specific for a fungicide that is found in the majority of the french wine: iprodione. The challenge for extracting iprodione from wine medium was that the hydoralcoholic solution is a dipolar solvent, whereas the interaction between the MIP and iprodione is based on dipolar interactions. The first extraction study of iprodione was made on a MIP synthesized by bulk polymerization using methacrylamide and ethylene glycol dimethacrylate (EGDMA). The MIP was found to be more efficient than the NIP (non-imprinted polymer) in hydroalcoholic solutions which demonstrates that the molecular imprinting was successful. Th…

Sorption isotherms[CHIM.GENI] Chemical Sciences/Chemical engineeringIprodioneWineIsothermes d’adsorptionAbsorption de l’eauExperimental designMISPEMIP[CHIM.GENI]Chemical Sciences/Chemical engineeringWater sorptionVinPesticides[ CHIM.GENI ] Chemical Sciences/Chemical engineeringPlan d’experiences
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